Effects of Heavy Deformation and Annealing on the Electrical Properties of Bi2Te3
作者:
J. M. Schultz,
J. P. McHugh,
W. A. Tiller,
期刊:
Journal of Applied Physics
(AIP Available online 1962)
卷期:
Volume 33,
issue 8
页码: 2443-2450
ISSN:0021-8979
年代: 1962
DOI:10.1063/1.1728990
出版商: AIP
数据来源: AIP
摘要:
Heavy plastic deformation producing nonbasal slip in Bi2Te3changes the material fromptype tontype and decreases its resistivity. From Hall coefficient measurements, it appears that an excess of about 2×1020negative carriers can be generated in the lattice. Annealing the deformed samples at different temperatures and in different environments causes large changes in this excess carrier concentration. A simple theoretical model based on point defect generation by the plastic deformation accounts for the results. From this model, it appears that tellurium vacancies are the predominant electrically active point defects. These Te vacancies are annihilated by dislocation climb and array formation during annealing. The effect of dissolved oxygen in Bi2Te3is to add donor states to the system.
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