Determination of Humic Substances in Seawater by Electrochemistry (Mechanisms)
作者:
F. Quentel,
C. Madec,
J. Courtot-coupez,
期刊:
Analytical Letters
(Taylor Available online 1987)
卷期:
Volume 20,
issue 1
页码: 47-62
ISSN:0003-2719
年代: 1987
DOI:10.1080/00032718708082236
出版商: Taylor & Francis Group
关键词: Humic substances;molybdenum(VI);adsorption and reduction mechanisms;adsorptive differential pulse voltammetry
数据来源: Taylor
摘要:
A new method for the measurement of the concentration of humic substances (HS) in seawater is described. The peak obtained by differential cathodic sweep voltammetry after HS adsorption in the presence of traces of molybdenum(VI) can be used for quantitative determination. Measurements using various electrochemical techniques (ACP, CV, ADPV, DPP) would indicate that the film adsorbed onto the electrode is the result of the adsorption of the organic substance in a first step followed in a subsequent step by the formation of a surface complex (Mo(VI)-HS)adsrather than the direct adsorption of the dissolved complex. The electrochemical mechanism corresponds to a one-electron reduction of the adsorbed (Mo(VI)-HS)adscomplex to the corresponding (Mo(V)-HS)adscomplex.
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