Interferometric measurements of the dipole polarizability α of molecules between 300 K and 1100 K
作者:
Uwe Hohm,
Klaus Kerl,
期刊:
Molecular Physics
(Taylor Available online 1990)
卷期:
Volume 69,
issue 5
页码: 803-817
ISSN:0026-8976
年代: 1990
DOI:10.1080/00268979000100611
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The temperature dependence of the dipole polarizability α(λ,T) of free atoms and molecules is determined by precise measurements of the refractive indexnof gases in the extended temperature range between 300 K and 1100 K for wavelength λ = 632·99 nm, using a specially constructed Michelson twin interferometer. α of the noble gases is observed to be independent ofT. α of the molecular gases H2, N2, O2, and CH4increases with increasing temperature by an amount of approximately 1 per cent per 1000 K. These results are in excellent agreement with theoretical predictions. They will be compared to previously measured temperature dependent polarizabilities.
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