Structure and Reduction Behavior of Platinum Chloride Intercalated in Graphite Layers
作者:
Masayuki Shirai,
Koichi Igeta,
Masahiko Arai,
期刊:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
(Taylor Available online 2000)
卷期:
Volume 340,
issue 1
页码: 127-130
ISSN:1058-725X
年代: 2000
DOI:10.1080/10587250008025454
出版商: Taylor & Francis Group
关键词: graphite intercalation compounds;platinum chloride;platinum metal particles;EXAFS
数据来源: Taylor
摘要:
Platinum chloride-graphite intercalation compounds (PtCl4-GICs) were synthesized from platinum chloride (PtCl4) and graphite under pressurized chlorine atmosphere. The analysis of XRD patterns showed that platinum chloride was inserted into graphite layers and the PtCI4-GICs with a stage 3 structure were formed. The curve-fitting analysis of Pt LIII-edge EXAFS showed that the distance of the Pt-Cl-Pt bond of 5 wt% PtCl4-GIC was 0.06 A longer than that of the PtCl4bulk, indicating that PtCl4had a distorted structure in graphite layers. PtCl4samples were reduced in hydrogen atmosphere to produce platinum metal particles in graphite layers. EXAFS analysis showed that the coordination numbers of Pt-Pt metal bond for PtCl4-GIC samples reduced at various temperatures were lower than those of the mixture of PtCl4and graphite (PtCl4-Gmix) samples reduced in the same manners.
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