Thermochemical Nitridation of Microporous Silica Films in Ammonia
作者:
RICHARD K. BROW,
CARLO G. PANTANO,
期刊:
Journal of the American Ceramic Society
(WILEY Available online 1987)
卷期:
Volume 70,
issue 1
页码: 9-14
ISSN:0002-7820
年代: 1987
DOI:10.1111/j.1151-2916.1987.tb04845.x
出版商: Blackwell Publishing Ltd
数据来源: WILEY
摘要:
Microporous silicon dioxide thin Films were deposited on silicon substrates from a solution of tetraethoxysilane, ethanol, and water. These were converted to dense oxynitrides through a high‐temperature reaction with ammonia. The ammonia treatments yielded amorphous, compositionally homogeneous films with overall nitrogen contents ranging up to 40 mol%. For ammonia treatments below 800°C, nitrogen was incorporated into the films as an amine species, whereas higher temperature treatments produced a nitride materi
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