Partial Quenching of Rare Earth Moment in Cubic Laves Intermetallic Compounds
作者:
M. J. McDermott,
K. K. Marklund,
期刊:
Journal of Applied Physics
(AIP Available online 1969)
卷期:
Volume 40,
issue 3
页码: 1007-1008
ISSN:0021-8979
年代: 1969
DOI:10.1063/1.1657505
出版商: AIP
数据来源: AIP
摘要:
Measurements of the low‐temperature (0.1° to 1.0°K) heat capacities of several cubic Laves intermetallic compounds containing praseodymium indicate the presence of a substantial nuclear hyperfine contribution to the specific heat. It is possible to relate the magnitude of this contribution to the magnetic moment carried by the Pr3+ion in each of the materials studied. The moments deduced in this way are PrNi2, 0.582±0.006; PrCo2, 2.18±0.05; PrAl2, 2.65±0.03 &mgr;B. These are each significantly less than the free Pr3+ionic moment of 3.20 &mgr;B. The results are discussed in terms of a theory of Bleaney and it is concluded that the crystalline electric field is the same in PrCo2and PrNi2, the large moment in the former being due to a larger exchange interaction. In the case of PrAl2, the data indicate an accidental degeneracy in the crystalline field ground state.
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