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The Structure and Dynamics of Liquids

 

作者: W. E. Roseveare,   R. E. Powell,   Henry Eyring,  

 

期刊: Journal of Applied Physics  (AIP Available online 1941)
卷期: Volume 12, issue 9  

页码: 669-679

 

ISSN:0021-8979

 

年代: 1941

 

DOI:10.1063/1.1712959

 

出版商: AIP

 

数据来源: AIP

 

摘要:

By coordinating our information on viscosity, diffusion, melting, and other rate and thermodynamic properties, we arrive at a detailed picture of liquid structure. Thus we find that a liquid is best thought of as a solid to which a large number of empty equilibrium positions are added. In fact the expansion on melting, as well as the expansion with a rise in temperature, arises almost entirely from this introduction of new equilibrium positions, and only to a minor extent from lattice expansion. We shall obtain information as to the number, size and energy of formation of these empty lattice points.

 

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