The Structure and Dynamics of Liquids
作者:
W. E. Roseveare,
R. E. Powell,
Henry Eyring,
期刊:
Journal of Applied Physics
(AIP Available online 1941)
卷期:
Volume 12,
issue 9
页码: 669-679
ISSN:0021-8979
年代: 1941
DOI:10.1063/1.1712959
出版商: AIP
数据来源: AIP
摘要:
By coordinating our information on viscosity, diffusion, melting, and other rate and thermodynamic properties, we arrive at a detailed picture of liquid structure. Thus we find that a liquid is best thought of as a solid to which a large number of empty equilibrium positions are added. In fact the expansion on melting, as well as the expansion with a rise in temperature, arises almost entirely from this introduction of new equilibrium positions, and only to a minor extent from lattice expansion. We shall obtain information as to the number, size and energy of formation of these empty lattice points.
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