Low temperature dynamic mechanical properties of polyurethane‐polyether block copolymers
作者:
J. L. Illinger,
N. S. Schneider,
F. E. Karasz,
期刊:
Polymer Engineering&Science
(WILEY Available online 1972)
卷期:
Volume 12,
issue 1
页码: 25-29
ISSN:0032-3888
年代: 1972
DOI:10.1002/pen.760120104
出版商: Society of Plastics Engineers, Inc.
数据来源: WILEY
摘要:
AbstractDynamical mechanical relaxation spectra of a number of polyurethane‐polyether block copolymers have been studied as a function of composition, temperature and frequency. At low temperatures these copolymers are characterized by a high glass‐like modulus which decreases to a much lower typically elastomeric value in a narrow temperature range. The latter is a function in certain cases of the composition of the polymer. The rubbery plateau is maintained up to at least 140°C. In addition, a secondary relaxation is observed around −130°C. These observations can be interpreted in terms of an overall structure consisting of a polyether matrix containing segregated polyurethane domains, the latter serving as physical crosslinks in the system at ambient temperatures an
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