Ultraviolet Spectrometric Determination of Phenols as Phenolate Anions
作者:
James Disinger,
StanleyE. Manahan,
期刊:
Analytical Letters
(Taylor Available online 1982)
卷期:
Volume 15,
issue 12
页码: 1017-1029
ISSN:0003-2719
年代: 1982
DOI:10.1080/00032718208064414
出版商: Taylor & Francis Group
关键词: Phenols;spectrophotometry;phenol analysis;phenolate ions;coal by-products
数据来源: Taylor
摘要:
The determination of phenols is important in many areas, such as the characterization of hazardous waste products and the analysis of coal gasification by-products and the analysis of coal gasification by-product waters. Ultraviolet spectrometric phenolate anion measurement is a simple and reliable technique for the selective determination of phenol concentrations in water. For most common phenols, the difference in absorptivity at 291 nm caused by raising the pH from 7 to 12 and converting unionized phenols to phenolate anions provides an accurate measure of phenol concentrations despite variable sample compositions. This technique may be applied directly to aqueous samples or to other samples after extraction of phenols with a solvent.
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