The effect of a lateral hydroxy substituent on the thermal stability of the chiral smectic C phase
作者:
RussellA. Lewthwaite,
JohnW. Goodby,
KennethJ. Toyne,
期刊:
Liquid Crystals
(Taylor Available online 1994)
卷期:
Volume 16,
issue 2
页码: 299-313
ISSN:0267-8292
年代: 1994
DOI:10.1080/02678299408029154
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
This article describes how the inclusion and positioning of a lateral hydroxy group influences the thermal stability of a chiral smectic C phase. An off-central position of the hydroxy group in the aromatic core has the effect of enhancing the thermal stability of the chiral smectic C phase, whereas a central position of the hydroxy group destabilizes it to the extent that there is no evidence for the phase being present. The results indicate that a hydroxy grouportho- to an ester function gives intra- rather than inter-molecular hydrogen bonding. The effects seen with lateral and terminal hydroxy groups are compared with those for analogous fluoro-substituted systems.
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