The Nonisothermal Crystallization Kinetics of Polypropylene After DSC Calibration on Cooling
作者:
J.A. MARTINS,
J.J. C. CRUZ PINTO,
期刊:
Journal of Macromolecular Science, Part B
(Taylor Available online 2000)
卷期:
Volume 39,
issue 5-6
页码: 711-722
ISSN:0022-2348
年代: 2000
DOI:10.1081/MB-100102482
出版商: Taylor & Francis Group
关键词: Calibration;Cooling;Crystallization;Kinetics;Nonisothermal
数据来源: Taylor
摘要:
The effect of the temperature scale on the nonisothermal crystallization of a polypropylene (PP) was studied with the Nakamura equation and a Tobin-type equation for nonisothermal crystallization. The calibration on cooling of differential scanning calorimetry (DSC) data was performed, and the scanning rate dependence of the sample’s thermal resistance was evaluated and taken into account to correct the nonisothermal crystallization data obtained from the DSC measurements. The description of the crystallization was performed with only one varying parameter, which changed regularly with the scanning rate, making possible predictions of real nonisothermal crystallization behavior at intermediate or high scanning rates.
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