首页   按字顺浏览 期刊浏览 卷期浏览 Preparation ofp‐type silicon films by plasma decomposition of a SiH4/H2/BF3gas m...
Preparation ofp‐type silicon films by plasma decomposition of a SiH4/H2/BF3gas mixture

 

作者: H. Kakinuma,   M. Mohri,   T. Tsuruoka,  

 

期刊: Journal of Applied Physics  (AIP Available online 1993)
卷期: Volume 74, issue 7  

页码: 4614-4619

 

ISSN:0021-8979

 

年代: 1993

 

DOI:10.1063/1.354380

 

出版商: AIP

 

数据来源: AIP

 

摘要:

p‐Type microcrystalline Si films have been prepared by rf decomposition of SiH4/H2/BF3gases. The gas composition, substrate temperature, and rf power dependence of film conductivity &sgr; are investigated. The &sgr; increases with increasing BF3and saturates or takes a maximum at [BF3]/[SiH4]∼1. A fairly high &sgr; value of ∼1.2×10−2S/cm is obtained for the low rf power (∼0.1 W/cm2). Increasing rf power decreases &sgr;, which is in contrast to the SiH4/H2/B2H6system. The incorporation rate of boron from gas phase into the film is found to be low (∼4%) by use of secondary ion mass spectroscopy. Increasing hydrogen increases &sgr;. Temperature is found to be the most effective deposition parameter. The &sgr; monotonically increases with an increase of substrate temperatureTS. Transmission electron microscopy observation shows that films with higher &sgr; contain higher density or larger size Si crystallites. The crystalline size increases by a short time (≤15 min) annealing at 400 °C. The deposition parameter dependence of &sgr; in comparison to the SiH4/H2/B2H6system is discussed. The low temperature annealing effect is discussed in terms of film structure.  

 

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