ANALYSIS OF CONCENTRATION FORCING IN HETEROGENEOUS CATALYSIS
作者:
JAN THULLIE,
LEROY CHIAO,
ROBERTG. RINKER,
期刊:
Chemical Engineering Communications
(Taylor Available online 1986)
卷期:
Volume 48,
issue 4-6
页码: 191-205
ISSN:0098-6445
年代: 1986
DOI:10.1080/00986448608911786
出版商: Taylor & Francis Group
关键词: Concentration forcing;Heterogeneous catalysis;Adsorption/desorption kinetic models
数据来源: Taylor
摘要:
An analysis of reaction rate enhancements by forced concentration oscillations of reactants for an adsorption/desorption type model with Eley-Rideal surface kinetics, is presented. Under cycling conditions in which the cycle time approaches zero, there is considerable rate enhancement relative to optimal steady state for nonlinear kinetics but no improvement for linear kinetics. The presence of inerts or products from irreversible reactions deteriorates the rate enhancement. For cycle times approaching infinity, there is no rate enhancement for either linear or nonlinear kinetics.
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