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ANALYSIS OF CONCENTRATION FORCING IN HETEROGENEOUS CATALYSIS

 

作者: JAN THULLIE,   LEROY CHIAO,   ROBERTG. RINKER,  

 

期刊: Chemical Engineering Communications  (Taylor Available online 1986)
卷期: Volume 48, issue 4-6  

页码: 191-205

 

ISSN:0098-6445

 

年代: 1986

 

DOI:10.1080/00986448608911786

 

出版商: Taylor & Francis Group

 

关键词: Concentration forcing;Heterogeneous catalysis;Adsorption/desorption kinetic models

 

数据来源: Taylor

 

摘要:

An analysis of reaction rate enhancements by forced concentration oscillations of reactants for an adsorption/desorption type model with Eley-Rideal surface kinetics, is presented. Under cycling conditions in which the cycle time approaches zero, there is considerable rate enhancement relative to optimal steady state for nonlinear kinetics but no improvement for linear kinetics. The presence of inerts or products from irreversible reactions deteriorates the rate enhancement. For cycle times approaching infinity, there is no rate enhancement for either linear or nonlinear kinetics.

 

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