Comparison of Partition Chromatographic Parameters of Lipophilic Organic Electrolytes for Solvents of Various Donor-Acceptor Properties. VII. Discussion of the Correlation Method from the Viewpoint of the Additivity Principle
作者:
Edward Soczewinski,
Wieslawa Maciejewicz,
期刊:
Separation Science
(Taylor Available online 1975)
卷期:
Volume 10,
issue 4
页码: 393-406
ISSN:0037-2366
年代: 1975
DOI:10.1080/00372367508058028
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
A graphical correlation method proposed by Rohrschneider and Littlewood for gas chromatography is applied to liquid-liquid partition of five homologous series of organic bases. The experimental data are interpreted in terms of the additivity ofRMvalues. Graphical estimation of partition coefficients of more complex molecules from group δRMsvalues and the correlation line of a simpler solute is described.
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