Polymerization of Vinyl Monomers in Organic Solutions of Cellulose
作者:
T. Graczyk,
V. Hornof,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1985)
卷期:
Volume 22,
issue 9
页码: 1209-1217
ISSN:0022-233X
年代: 1985
DOI:10.1080/00222338508063329
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Methyl methacrylate and other monomers were polymerized in systems involving cellulose completely or partially dissolved in complex solvents. Both the system [dimethylsulfoxide-sulfur dioxide] and the system [dimethylformamide-copper nitrate-cumene hydroperoxide] were found to be effective in initiating polymerization. In the presence of air, cellulose seemed to counteract the inhibiting effect of oxygen. All the reactions resulted in the formation of homopolymer only, and no graft co-polymers of cellulose were detected in the products.
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