AbstractThe seven new substances, isolated from the seeds ofVallaris solanacea(ROTH) O. K., have been shown to have the following structures:Vallaroside (substance D) = digitoxigenin‐α‐L‐vallaropyranoside, solanoside (substance F) = digitoxigenin‐α‐L‐acofriopyranoside, vallarosolanoside (substance E) = oleandrigenin‐α‐L‐vallaropyranoside, 16‐deacetyl‐16‐anhydro‐acoschimperoside P (substance H) = 16‐anhydro‐g