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Some Aspects of the Splitting of Ionic Energy Levels in Crystals

 

作者: Hans E. Band,  

 

期刊: American Journal of Physics  (AIP Available online 1964)
卷期: Volume 32, issue 7  

页码: 529-542

 

ISSN:0002-9505

 

年代: 1964

 

DOI:10.1119/1.1970764

 

出版商: American Association of Physics Teachers

 

数据来源: AIP

 

摘要:

Bethe's early group-theoretical treatment is supplemented by some physical arguments illustrating his method of semiquantitative evaluation of the term splitting. Up to date notations are introduced. The cases of weak, intermediate, and strong crystal-field splitting are discussed, with typical ions given as examples. For cubic and hexagonal site symmetry, the Bethe method is demonstrated step-by-step and the results applied to transition metal ions. Double-valued group representations, double groups and Kramers degeneracy are introduced, compared, and illustrated with physical examples. Certain mathematical analogies between formulas of representation theory and angular momentum theory are pointed out.

 

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