Molecular-Orbital Calculation on the Neutral Mixed-Valent Platinum Complex [PtIICl2(en)][PtIVCl4(en)]
作者:
Tokutaro Komatsu,
Norimichi Kojima,
期刊:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
(Taylor Available online 2000)
卷期:
Volume 342,
issue 1
页码: 139-144
ISSN:1058-725X
年代: 2000
DOI:10.1080/10587250008038257
出版商: Taylor & Francis Group
关键词: mixed-valent complex;platinum complex;non-linear excitation;extended Hückel calculation;density-functional method
数据来源: Taylor
摘要:
The character of the photo-induced metastable state is investigated via molecular-orbital calculation. The anisotropic g-factor and the hyperfine coupling constants are simulated based on the extended-Hückel calculation. The most plausible environment around the metastable PtIIIis found to be a spin-soliton like state, whose spin-orbital mainly comprises one platinum and one chlorine atoms. The vibration mode of the elemental unit of the complex is calculated for both high- and low-temperature structures employing a density-functional method.
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