Methylene dichloride and 1 :2‐dichloroethane. I. Solubility of water. II. Vapour pressure
作者:
W. Davies,
J. B. Jaggeh,
H. K. Whalley,
期刊:
Journal of the Society of Chemical Industry
(WILEY Available online 1949)
卷期:
Volume 68,
issue 1
页码: 26-31
ISSN:0368-4075
年代: 1949
DOI:10.1002/jctb.5000680108
出版商: John Wiley&Sons, Ltd
数据来源: WILEY
摘要:
AbstractThe solubility of water in methylene chloride and I: 2‐dichloro‐ethane over the temperature range ‐ 20° to 40° and 80° respectively has been determined. The vapour pressures of the solvents, alone and in admixture, have been measured, and the composition of the varour phases of the mixed solvents determined at 10° intervals. over the range 20‐50°. Evidence of the formation of azeotropes with water is given; boiling point: composition and vapour pressure: boiling point relationships are derived. Mixtures of the two solvents are found closely to obey Raoult's law. The results are discussed in the light of Hildebrand's theor
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