Graft Polymerization of 2-Hydroxyethyl Methacrylate onto Plasma Pretreated Cotton, Silk, and Polyester Fibers
作者:
Toshihiro Hirotsu,
Norio Asai,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1991)
卷期:
Volume 28,
issue 5-6
页码: 461-473
ISSN:0022-233X
年代: 1991
DOI:10.1080/00222339108052100
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Graft polymerization of 2-hydroxyethyl methacrylate was made onto plasma pretreated fabrics of cotton, silk, and polyester. Homopolymerization also took place during the graft polymerization, but the percent of the homopolymer formation was comparatively small. Therefore, kinetic analyses of graft polymerization were undertaken based on the first-order reaction of the monomer. Through a comparison of the rate constants which were obtained from the rate equation of the graft polymerization of 2-hydroxyethyl methacrylate, the dependence of plasma pretreatment on various factors and the resulting polymerization were clarified. Polymerizability was compared to that obtained with the Ce(IV) catalyst and without catalysts.
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