Phonon dispersion in helical s(2/1)2 syndiotactic polystyrene
作者:
Shantanu Rastogi,
V.D. Gupta,
期刊:
Journal of Macromolecular Science, Part B
(Taylor Available online 1995)
卷期:
Volume 34,
issue 1-2
页码: 1-13
ISSN:0022-2348
年代: 1995
DOI:10.1080/00222349508219484
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Phonon dispersions for helical s(2/l)2 syndiotactic polystyrene (sPS) are obtained and compared with the dispersions for its planar form. Optically active frequencies corresponding to the zone center and zone boundary are identified and discussed. In general the dispersion in the helical form is less as compared to the planar form. Some of the distinguishing features such as crossing over, repulsion of modes, and profile of the acoustic modes are discussed and possible explanations are given.
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