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Phonon dispersion in helical s(2/1)2 syndiotactic polystyrene

 

作者: Shantanu Rastogi,   V.D. Gupta,  

 

期刊: Journal of Macromolecular Science, Part B  (Taylor Available online 1995)
卷期: Volume 34, issue 1-2  

页码: 1-13

 

ISSN:0022-2348

 

年代: 1995

 

DOI:10.1080/00222349508219484

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Phonon dispersions for helical s(2/l)2 syndiotactic polystyrene (sPS) are obtained and compared with the dispersions for its planar form. Optically active frequencies corresponding to the zone center and zone boundary are identified and discussed. In general the dispersion in the helical form is less as compared to the planar form. Some of the distinguishing features such as crossing over, repulsion of modes, and profile of the acoustic modes are discussed and possible explanations are given.

 

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