A comparison of the dynamic mechanical relaxation behavior of linear low- and high-density polyethylenes
作者:
R.G. Matthews,
A.P. Unwin,
I.M. Ward,
G. Capaccio,
期刊:
Journal of Macromolecular Science, Part B
(Taylor Available online 1999)
卷期:
Volume 38,
issue 1-2
页码: 123-143
ISSN:0022-2348
年代: 1999
DOI:10.1080/00222349908248110
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The mechanical relaxation behaviors of oriented samples of a linear low-density polyethylene (LLDPE) and a high-density polyethylene (HDPE) were studied using tensile dynamic mechanical measurements. The anisotropy and activation energies of the relaxations were determined for several different samples to investigate why the α-relaxation in HDPE has characteristics similar in some respects to both the α- and β-relaxations in LLDPE. It is concluded that the anisotropy of the α-relaxation in LLDPE is determined byc-shear, whereas in HDPE it relates to interlamellar shear. The activation energy measurements, however, show that the thermally activated process for the α-relaxation in both the LLDPE and HDPE isc-shear. It is proposed that, in HDPE,c-shear has to occur before there is enough mobility at the fold surface for interlamellar shear. It is concluded that the β-relaxation is not observed in HDPE because the interlamellar regions are too constrained to allow interlamellar shear withoutc-shear.
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