New interpretations for stress-strain behavior of rubber vulcanizates
作者:
Akihiro Suzuki,
Hidetoshi Oikawa,
Kenkichi Murakami,
期刊:
Journal of Macromolecular Science, Part B
(Taylor Available online 1984)
卷期:
Volume 23,
issue 4-6
页码: 535-547
ISSN:0022-2348
年代: 1984
DOI:10.1080/00222348408219476
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The cross-link density of DCP-cured natural rubber uniaxially deformed to various extension ratios at room temperature was measured. The cross-link density decreased characteristically with increasing extension ratio. A new model for the structure of the network is proposed in order to explain this decrease in cross-link density. The model can give a new interpretation of the stress-strain behavior of rubber vulcanizates. The birefringence of stretched rubber vulcanizates was determined using a polarizing microscope. The observed birefringence, δT, can generally be factored into two parts: One is the birefringence of the amorphous phase, δTa; the other is the birefringence due to the strain-induced crystalline phase, δTc. In the present paper, it has become feasible to separate δT into δTaand δTc.
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