AbstractArchaean greenstone belts are often cut by major shear zones, for example the Cadillac tectonic zone (CTZ) of the southern Abitibi region in north‐western Quebec. At McWatters, the CTZ contains slices of metavolcanic units bounded by corridors of highly strained and altered rocks. Mineral assemblages of the metabasites record the metamorphic evolution of the CTZ.The McWatters metabasalts and metagabbros have similar chemistry but different mineral assemblages consisting of variable amounts of actinolite, hornblende, chlorite, albite, epidote, quartz, carbonates, titanite, biotite, rutile, magnetite, ilmenite and sulphides. The different mineral assemblages, which coexist in a single tectonic slice, can be divided into three types, characterized by (A) presence of hornblende and actinolite, (B) presence of actinolite and epidote, and (C) absence of amphibole and epidote. Partial replacements indicate that these mineral assemblages are not in equilibrium. The hornblende of the least altered and deformed samples of the type A assemblage is a relict of a prograde metamorphic event, contemporaneous with the development of the main schistosity. The prograde conditions are estimated atP= 5 kbar,T= 475° C with lowPf. The more altered and deformed samples of the type C assemblage record a later retrograde metamorphic event. Conditions of the later event are estimated atP= 4 kbar,T= 400° C with higherPf. Widespread calcite precipitation occurred during a later episode. The diversity of the mineral assemblages results from permeability variations along the high‐strain zones of th