Note Synthesis and Characterization of Poly-(2-Methallyl-p-cresol)
作者:
P. Rajalingam,
G. Radhakrishnan,
M.S. Lucia,
D. Kalyanasundaram,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1989)
卷期:
Volume 26,
issue 10
页码: 1471-1474
ISSN:0022-233X
年代: 1989
DOI:10.1080/00222338908052064
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
In spite of the low reactivity of allyl monomers, attempts have been made to prepare polymers by polyrecombination of allyl aromatic compounds. We were encouraged by the stability of allyl radicals [1-8]. The literature on the Claisen rearrangement of polyfunctional allyl aryl ethers contains some observations of the formation of tarry masses and resinification of polyfunctional aryl ethers. Details of the polymerization and the possible structures were not studied. We felt it interesting to synthesize this new monomer, 2-methyallyl-p-cresol, by the rearrangement, and to study in detail the polymerization and characterization of the polymer.
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