On the continuity of isochore slopes, and the divergence of the curvature of the vaporization curve at the critical point of a simple fluidf
作者:
John Stephenson,
期刊:
Physics and Chemistry of Liquids
(Taylor Available online 1976)
卷期:
Volume 6,
issue 1
页码: 55-69
ISSN:0031-9104
年代: 1976
DOI:10.1080/00319107608085060
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The role of the exponent inequality β + γ > I in the continuity of (∂P/∂T), with the slope of the vaporization curve at the critical point is discussed. A connection between the divergence in the curvature of the vaporization curve and asymmetries in certain thermodynamic functions is established. It is shown, in the context of the scaling law equation of state, that the homogeneous phase specific heat C(1)Von the liquid branch of the coexistence curve is slightlylowerthan on the gas branch, at the same temperature.
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