首页   按字顺浏览 期刊浏览 卷期浏览 Coupled diffusion of butanol solubilized in aqueous sodium dodecylsulfate micelles
Coupled diffusion of butanol solubilized in aqueous sodium dodecylsulfate micelles

 

作者: Derek G. Leaist,  

 

期刊: Canadian Journal of Chemistry  (NRC Available online 1990)
卷期: Volume 68, issue 1  

页码: 33-35

 

ISSN:0008-4042

 

年代: 1990

 

DOI:10.1139/v90-008

 

出版商: NRC Research Press

 

数据来源: NRC

 

摘要:

Ternary interdiffusion coefficients have been measured for ten compositions of the system sodium dodecylsulfate (NaDS) + 1-butanol (BuOH) + water at 25 °C. The diffusivity of BuOH in this system is lower than in pure water because about one half of the alcohol is solubilized in the slowly-diffusing NaDS micelles. Yet, surprisingly, diffusion of the NaDS component transports only minor amounts of BuOH. Diffusion of the BuOH component, however, produces a substantial coupled flow of NaDS. Although added BuOH increases the solution viscosity and the size of the micelles, the diffusivity of the NaDS component does not change significantly. The Harned restricted diffusion method for the determination of electrolyte diffusivities is extended to electrolyte + nonelectrolyte solutes.Keywords: micelles, ionic; solubilization; diffusion, coupled.

 

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