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Optical Studies of the Monolayer Films of Diazole-Containing Porphyrins at the Air-Water Interface

 

作者: Chusaku Ikeda,   Yufuko Takashima,   Takeshi Irie,   Naoki Yoshioka,   Hidenari Inoue,  

 

期刊: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals  （Taylor Available online 2000）
卷期: Volume 342, issue 1  

页码: 81-86

 

ISSN:1058-725X

 

年代: 2000

 

DOI:10.1080/10587250008038248

 

出版商: Taylor & Francis Group

 

关键词: porphyrin;pyrazole;imidazole;monolayer;coordination;supramolecular chemistry

 

数据来源: Taylor

 

摘要:

Optical properties of the monolayers of 5-(1-methyliniidazol-2-yl)- 10,15,20-tris(p-octyloxy-phenyl)porphyrin, 5-(1-methylpyrazol-4-yl)-10,15,20-tris(p-octyloxyphenyl)porphyrin and their zinc(II) complexes have been studied. The π-A isotherms and UV-vis spectra have revealed that the zinc(II) complexes form coordination assemblies between peripheral nitrogen atom and central zinc(II) ion at the air-water interface with very tight molecular packing.

 

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