首页   按字顺浏览 期刊浏览 卷期浏览 Studies in anthracyclinone synthesis. The oxidative decyanation route to aklavinone and...
Studies in anthracyclinone synthesis. The oxidative decyanation route to aklavinone and 4,11-dideoxy-α-rhodomycinone

 

作者: J. Appa Rao,   K. Ravichandran,   G. J. O'Malley,   M. P. Cava,  

 

期刊: Canadian Journal of Chemistry  （NRC Available online 1987）
卷期: Volume 65, issue 1  

页码: 31-34

 

ISSN:0008-4042

 

年代: 1987

 

DOI:10.1139/v87-007

 

出版商: NRC Research Press

 

数据来源: NRC

 

摘要:

The formal synthesis of aklavinone and the first synthesis of 4,11-dideoxy-α-rhodomycinone are described. Oxidative decyanation of the tetracyclic nitrile to the corresponding ketone using a strong base (LDA) constitutes an important strategy in the synthesis of both these compounds.

 

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