Unsaturated acids containing a trifluoromethyl group
作者:
I.L.Knunyants,
Yu.A.Cheburkov,
期刊:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science
(Springer Available online 2004)
卷期:
Volume 10,
issue 6
页码: 977-981
ISSN:0568-5230
年代: 2004
DOI:10.1007/BF00909170
出版商: Springer_US-Boston
数据来源: Springer
摘要:
1.β-Trifluoromethylcrotonic acid was obtained by the action of anhydrous sulfuric acid on β-trifluoromethyl-β-methylpropiolactone or β-trifluoromethyl-β-hydroxybutyric acid.2.Thionyl chloride in distinction from phosphorus pentoxide easily dehydrates methyl β-trfluoromethyl-β-hydroxybutyrate.3.After studying the direction of addition of methanol,ammonia, and ethanolamine to esters of β-trifluoromethylcrotonic acid it was concluded that the deciding role in the addition of nucleophilic reagents was played by polarization of the double bond, not steric hi
点击下载:
PDF
(332KB)
返 回