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Unsaturated acids containing a trifluoromethyl group

 

作者: I.L.Knunyants,   Yu.A.Cheburkov,  

 

期刊: Bulletin of the Academy of Sciences of the USSR, Division of chemical science  (Springer Available online 2004)
卷期: Volume 10, issue 6  

页码: 977-981

 

ISSN:0568-5230

 

年代: 2004

 

DOI:10.1007/BF00909170

 

出版商: Springer_US-Boston

 

数据来源: Springer

 

摘要:

1.β-Trifluoromethylcrotonic acid was obtained by the action of anhydrous sulfuric acid on β-trifluoromethyl-β-methylpropiolactone or β-trifluoromethyl-β-hydroxybutyric acid.2.Thionyl chloride in distinction from phosphorus pentoxide easily dehydrates methyl β-trfluoromethyl-β-hydroxybutyrate.3.After studying the direction of addition of methanol,ammonia, and ethanolamine to esters of β-trifluoromethylcrotonic acid it was concluded that the deciding role in the addition of nucleophilic reagents was played by polarization of the double bond, not steric hi

 

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