On the Mechanism of Stationary Phase Retention in Rotating Coil Columns
作者:
P.S. Fedotov,
V.A. Kronrod,
T.A. Maryutina,
B.Ya. Spivakov,
期刊:
Journal of Liquid Chromatography & Related Technologies
(Taylor Available online 1996)
卷期:
Volume 19,
issue 20
页码: 3237-3254
ISSN:1082-6076
年代: 1996
DOI:10.1080/10826079608014576
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
A hypothesis of the mechanism of the retention of one (stationary) phase of a two-phase liquid system in a rotating coil column has been proposed. The balance of forces of different nature acting on the stationary phase retained in the coil column has been considered. The basic equation of the retention process stationarity has been derived. Theoretical dependencies of retention factor on rotational speed for hydrophobic systems and experimental data are in good agreement.
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