The Velocity Constants of Free Ions and Ion Pairs. II
作者:
Yoshinobu Tanaka,
Norio Ise,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1970)
卷期:
Volume 4,
issue 4
页码: 851-871
ISSN:0022-233X
年代: 1970
DOI:10.1080/00222337008060985
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The distribution of the intercharge distance of ion pairs was derived from a solvated ion pair model. The calculation was applied to a fluorenylsodium-tetrahydrofuran system, and the equilibrium constants for the equilibria, contact ion pairs solvent separated ion pairs free ions, were calculated. Furthermore, the enthalpy and entropy changes for the equilibria were derived. Agreement with experimental data was satisfactory.
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