Optical Kerr‐effect measurement for a series of alcohols
作者:
Neil J. Harrison,
Barry R. Jennings,
期刊:
Journal of Applied Physics
(AIP Available online 1993)
卷期:
Volume 73,
issue 12
页码: 8076-8080
ISSN:0021-8979
年代: 1993
DOI:10.1063/1.353923
出版商: AIP
数据来源: AIP
摘要:
Nanosecond optical Kerr‐effect (OKE) measurements are reported using a modified apparatus, designed to enable rapid and precise data recording in pure liquids. Careful design of the apparatus enables measurements to be made at several inducing wavelengths without substantial apparatus modifications. The first measurement of the optical Kerr effect for benzene at an inducing wavelength of 532 nm is presented together with novel OKE data for the hitherto unstudied homologous alcohol series from methanol to 1‐dodecanol. Analysis of the results indicates for this series the existence of a linear relationship between the carbon chain length and the optically induced Kerr constant somewhat similar to the behavior previously observed in then‐alkanes.
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