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Annealing of deformed polymers under dimensional constraint

 

作者: Teh‐Ming Kung,   J. C. M. Li,  

 

期刊: Journal of Applied Physics  (AIP Available online 1986)
卷期: Volume 60, issue 8  

页码: 2659-2664

 

ISSN:0021-8979

 

年代: 1986

 

DOI:10.1063/1.337092

 

出版商: AIP

 

数据来源: AIP

 

摘要:

The two‐stage process discovered in the recovery of deformed amorphous polymers (PS, PMMA, and PC) is verified in this study. The first stage which takes place belowTgreleases part of the stored energy (part 1) and recovers the volume. The second stage which takes place aboveTgreleases the rest of the stored energy (part 2) and recovers the dimension. The relation between the part 2 stored energy and dimensional changes during deformation is the same as that during recovery. In this study, the dimension is constrained not to change during recovery. As expected, the part 2 stored energy is not released but the part 1 stored energy is released as usual. Furthermore, if in a second scan the constraint is removed and the dimension is allowed to recover, the part 2 stored energy is then released. These results confirm the unique relationship between dimension and the part 2 stored energy and the separability of the two‐stage recovery process.

 

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