Hydrothermal Degradation and Kinetic Studies of 1,3-Dihydroxy-2-Propanone and 2,3-Dihydroxypropanal
作者:
Guenther Bonn,
Martin Rinderer,
Ortwin Bobleter,
期刊:
Journal of Carbohydrate Chemistry
(Taylor Available online 1985)
卷期:
Volume 4,
issue 1
页码: 67-77
ISSN:0732-8303
年代: 1985
DOI:10.1080/07328308508062949
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The equilibrium of 1,3-dihydroxy-2-propanone (dihydroxyacetone) and 2,3-dihydroxypropanal (glyceraldehyde) and their dehydration reaction to methylglyoxal has been studied in the range of 180 - 240 °C under hydrothermal reaction conditions. A reaction mechanism for the conversion of these C-3 compounds was formulated which allowed the calculation of the product yields. In the investigated temperature range both compounds produce a maximum of 30-40% of methylglyoxal.
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