A successful attempt to grow the Pd–Te intermetallic compounds on 2H–MoS2(0001) surfaces by molecular beam epitaxy will be reported. When a Te2molecular beam alone impinges onto the 2H–MoS2(0001) substrate, the sticking coefficient is found to decrease with increasing substrate temperature (Ts) and to become zero atTs≥470 K. The sticking coefficient of the Te2molecules impinging simultaneously with a Pd beam, however, is finite even at temperatures above 470 K. Under the simultaneous impinging condition, three kinds of intermetallic compounds: PdTe2(001), PdTe(001), Pd9Te4(010) are found to grow heteroepitaxially. The phase formed in the film depends on the flux ratio and the substrate temperature. The resultant phase diagram is explained quantitatively by considering a capture rate of Te molecules by the arriving Pd atoms.