The surface tension of polyethylene
作者:
H. W. Starkweather,
期刊:
Polymer Engineering&Science
(WILEY Available online 1965)
卷期:
Volume 5,
issue 1
页码: 5-6
ISSN:0032-3888
年代: 1965
DOI:10.1002/pen.760050102
出版商: Society of Plastics Engineers, Inc.
数据来源: WILEY
摘要:
AbstractExtrapolation from data on low molecular weight n‐alkanes indicates that the surface tension of polyethylene at 150°C is 26 dynes/cm. The total surface energy, γ — Tdγ/dT, is 51 dynes/cm and is much less dependent on chain length. The surface tension of polyethylene extrapolated to 20°C is 34 dynes/cm, consistent with the critical surface tension below which liquids will wet the polymer. The total surface energy is in reasonable accord with the incremental energy of vaporization, 1.029 kcal/mole of CH2groups. The surface entropy is less than that of low molecular substances. This is attributed to a reduction in the opportunities for rotational isomerism at the
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