λ-Shaped mesogens. Structure, phase formation and properties
作者:
D. Braun,
M. Reubold,
L. Schneider,
M. Wegmann,
J.H. Wendorff,
期刊:
Liquid Crystals
(Taylor Available online 1994)
卷期:
Volume 16,
issue 3
页码: 429-443
ISSN:0267-8292
年代: 1994
DOI:10.1080/02678299408029168
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
This contribution is concerned with molecules composed of rigid linear segments which are connected in such a way that a λ-shape results. Such types of shape have been predicted to lead to an enhanced solubility in low molar mass solvents and in the melt state of flexible chain molecules. The theoretical treatment predicted additionally that such molecules should be able to form lyotropic and thermotropic liquid crystalline phases. Experimental data on the thermodynamic properties, the structure formation in the solid and fluid condensed state, the solubility in low molar mass solvents and selected optical and electro-optical properties are reported; these are in good agreement with the predictions.
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