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A rheo‐optical study of near‐critical polymer solutions under oscillatory shear flow

 

作者: Janet Lai,   Gerald G. Fuller,  

 

期刊: Journal of Rheology  (AIP Available online 1995)
卷期: Volume 39, issue 5  

页码: 893-906

 

ISSN:0148-6055

 

年代: 1995

 

DOI:10.1122/1.550623

 

出版商: The Society of Rheology

 

关键词: DICHROISM;OSCILLATIONS;PHASE TRANSFORMATIONS;PHTHALATES;POLARIMETRY;POLYMERS;POLYSTYRENE;SOLUTIONS;STRESS RELAXATION

 

数据来源: AIP

 

摘要:

The flow‐induced structure and dynamics of concentration fluctuations in a near‐critical polymer solution have been investigated using the technique of polarimetry. Specifically, this article presents scattering dichroism of a single‐phased, semidilute solution of polystyrene in dioctyl phthalate (PS/DOP) subjected to small amplitude oscillatory shear flow. The measured frequency response is compared to results obtained using the Onuki–Doi theory, which relates dichroism to structure factor, and the Helfand–Fredrickson model, from which the structure factor is calculated. The predictions are in good qualitative agreement with the experimental data when stress relaxation is taken into account in the constitutive equation relating stress to strain in the system. Our results demonstrate that the strength of the coupling between viscoelastic stress and flow governs the behavior of concentration fluctuations in semidilute polymer solutions under oscillatory shear flow.

 

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