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SUSPENSION POLYMERIZATION

 

作者: H.G. Yuan,   G. Kalfas,   W.H. Ray,  

 

期刊: Journal of Macromolecular Science, Part C  (Taylor Available online 1991)
卷期: Volume 31, issue 2-3  

页码: 215-299

 

ISSN:1532-1797

 

年代: 1991

 

DOI:10.1080/15321799108021924

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

In a typical suspension polymerization system, one or more water-insoluble monomers containing oil-solube initiator(s) are dispersed in the continuous aqueous phase by a combination of strong stirring and the use of small amounts of suspending agents (stabilizers). Suitable conditions of mechanical agitation are maintained while the monomer droplets are slowly converted from a highly mobile liquid state, through a sticky syrup-like dispersion (conversion 20–60%), to hard solid polymer particles (conversion > 70%) [1–3]. The stabilizers hinder the coalescence of the monomer droplets first, and later stabilize tHe polymer beads whose tendency to agglomerate may become critical when the polymerization has advanced to the point where the polymer beads become sticky.

 

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