Thermodynamic Properties of Liquid Water up to 8000 Bar and Between 25 and 150°C
作者:
Bongkee Cho,
Kyu-Yong Choi,
Soon-Don Choi,
期刊:
Physics and Chemistry of Liquids
(Taylor Available online 1991)
卷期:
Volume 23,
issue 3
页码: 151-161
ISSN:0031-9104
年代: 1991
DOI:10.1080/00319109108027252
出版商: Taylor & Francis Group
关键词: Thermal properties of water
数据来源: Taylor
摘要:
A simple equation of state for the condensed phase, proposed by Cho, is applied to liquid water under pressure up to 8000 bar and between 25 and 150°C. The agreement between measured and calculated volumes is satisfactory over the entire range of temperatures and pressures. The equation shows that the abnormalities in the temperature and pressure dependence of the thermal expansivity, isothermal compressibility and the heat capacity are predicted quite accurately from PVT data only. The values of thermal expansivity, isothermal compressibility, and heat capacity at constant pressure are calculated, and detailed comparisons with the experimental values are made.
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