首页   按字顺浏览 期刊浏览 卷期浏览 Chiroptical Properties of Fluorescamine Derivatives of Chiral Primary Aminesin situ
Chiroptical Properties of Fluorescamine Derivatives of Chiral Primary Aminesin situ

 

作者: V. Toome,   B. Wegrzynski,   J. Dell,  

 

期刊: Spectroscopy Letters  （Taylor Available online 1977）
卷期: Volume 10, issue 9  

页码: 747-756

 

ISSN:0038-7010

 

年代: 1977

 

DOI:10.1080/00387017708065008

 

出版商: Taylor & Francis Group

 

关键词: CD spectra;absolute configuration;chiral primary amines

 

数据来源: Taylor

 

摘要:

Primary amines react efficiently with fluorescamine (FLURAM®) to form pyrrolinone-type chromophores with long wavelength absorption maxima at 380–410 nm. When the primary amine is chiral, these chromophoric derivatives exhibit characteristic Cotton effects. The chiroptical properties of the reaction mixtures can be related to the absolute configuration of the amines without isolation of the products.

 

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