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Kinetics Analysis by Digital Parameter Estimation

 

作者: Y. Bard,   L. Lapidus,  

 

期刊: Catalysis Reviews  (Taylor Available online 1969)
卷期: Volume 2, issue 1  

页码: 67-112

 

ISSN:0161-4940

 

年代: 1969

 

DOI:10.1080/01614946908066540

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

One of the more important problems that a chemist or chemical engineer may encounter is the determination of the mechanism and/ or model for a chemical reaction system. This problem may be encompassed within the broader area of identification [30–32] which ranges from the one extreme where no a priori information regarding the system representation is known, to the other extreme where much is known about the system. The development of a suitable chemical kinetic representation for the experimental reaction system lies somewhere between these two extremes. This results from the fact that there usually exist certain postulated models to represent experimental kinetic data; however, the determination of the best constants in these mechanistic models and perhaps the discrimination among a number of alternative models usually remain as vexing questions.

 

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