Modelling of Chlorophenol Treatment in Aqueous Solutions. 2. Ozonation under Basic Conditions
作者:
Marjaana Hautaniemi,
Juha Kallas,
Rein Munter,
Marina Trapido,
Arto Laari,
期刊:
Ozone: Science & Engineering
(Taylor Available online 1998)
卷期:
Volume 20,
issue 4
页码: 283-302
ISSN:0191-9512
年代: 1998
DOI:10.1080/01919519808547265
出版商: Taylor & Francis Group
关键词: Ozone;Ozonation;Chlorophenols;2-Chlorophenol;4-Chlorophenol;2,4-Dichlorophenol;Modelling
数据来源: Taylor
摘要:
Ozonation of 2-chlorophenol (2-CP), 4-chlorophenol (4-CP) and 2,4-dichlorophenol (2,4-DCP) in basic aqueous solutions is discussed. In such conditions (pH=9.5), ozonation of chlorophenols proceeds rapidly due to the presence of the dissociated form of the phenolic compound. No ozone occurs in the bulk of the liquid and, in modelling, it becomes necessary to account for the reactions in the liquid film. Two approaches were tested: 1) the film and bulk balances were solved sequentially, and the diffusional fluxes coupling the balances were obtained by solving numerically the concentration profiles in the film; 2) the bulk mass balances were solved without the film mass balances by applying the enhancement factor calculated from existing correlations. The results of both approaches are compared with experimental data. The formation mechanism of an aromatic quinone, hydrogen peroxide and chloride ions during the ozonation appeared to differ under basic conditions from that under acidic conditions. Hydroxyl radical reactions did not, however, have any effect on the chlorophenol decomposition.
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