A spectrophotometric method for determining small quantities of titanium by extraction of the yellow coloured titanium salicylamidoxime complex from an acetate buffer medium (Ph4.5–7.0) with iso-butanol and measurement of the colour intensity at 400 mμhas been described.Beer's law is obeyed in the entire range of 0.25–15μgTi per ml of the solvent. The effect of a large number of foreign anions and cations on the determination of titanium has been desc