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The quantum defect: Early history and recent developments

 

作者: A. R. P. Rau,   Mitio Inokuti,  

 

期刊: American Journal of Physics  (AIP Available online 1997)
卷期: Volume 65, issue 3  

页码: 221-225

 

ISSN:0002-9505

 

年代: 1997

 

DOI:10.1119/1.18532

 

出版商: American Association of Physics Teachers

 

关键词: RYDBERG STATES;HISTORICAL ASPECTS;QUANTUM MECHANICS;ELECTRONIC STRUCTURE;EXCITED STATES;PHASE SHIFT;POTENTIAL ENERGY;SPECTROSCOPY;01.65;30.

 

数据来源: AIP

 

摘要:

The notion of the quantum defect is important in atomic and molecular spectroscopy and also in unifying spectroscopy with collision theory. In the latter context, the quantum defect may be viewed as an ancestor of the phase shift. However, the origin of the term “quantum defect” does not seem to be explained in standard textbooks. It occurred in a 1921 paper by Schrödinger, preceding quantum mechanics, yet giving the correct meaning as an index of the short-range interactions with the core of an atom. We present the early history of the quantum-defect idea, and sketch its recent developments.

 

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