(DCNQI)2Cu: Variety of Magnetism Arising from pπ-d Interactions
作者:
Masafumi Tamura,
Hiroshi Sawa,
Yoshiaki Kashimura,
Shuji Aonuma,
Reizo Kato,
Minoru Kinoshita,
期刊:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
(Taylor Available online 1995)
卷期:
Volume 271,
issue 1
页码: 13-18
ISSN:1058-725X
年代: 1995
DOI:10.1080/10587259508034034
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Recent advances of our study of magnetic properties of a series of molecular conductors, Cu salts of DCNQIs, are presented. First, we have found weak ferromagnetism in the antiferromagnetically ordered state of Cu spins in the insulating phase. Second, the metal-insulator (M-I) transitions of these systems have been characterized by the abrupt change of Cu 3d spins from the itinerant state to the completely localized state, even in the metal-insulator-metal (M-I-M) reentrant system, (DMe-DCNQI-α,α'-d2)2Cu. Finally, (DI-DCNQI)2Cu is found to exhibit enhanced and temperature dependent susceptibility, suggesting the effect of spin fluctuations of itinerant electrons in a Cu 3d narrow band.
点击下载:
PDF (356KB)
返 回