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Functional polycarbonate by copolymerization of carbon dioxide and epoxide: Synthesis and hydrolysis

 

作者: Midori Takanashi,   Yoshihiro Nomura,   Yasuhiko Yoshida,   Shohei Inoue,  

 

期刊: Die Makromolekulare Chemie  （WILEY Available online 1982）
卷期: Volume 183, issue 9  

页码: 2085-2092

 

ISSN:0025-116X

 

年代: 1982

 

DOI:10.1002/macp.1982.021830907

 

出版商: Hüthig&Wepf Verlag

 

数据来源: WILEY

 

摘要:

AbstractPolycarbonates with pendant carbonate groups were synthesized by copolymerization of carbon dioxide and epoxides containing a carbonate substituent using the diethylzinc/water system as catalyst. The polycarbonates underwent acidic and basic hydrolysis to release slowly the compound attached as the pendant group via the carbonate linkage. Other hydrolysis products were glycerol and CO2, but no oligomeric products were formed.

 

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