Reductions with sulfurated borohydrides. IV. Reduction of oximes
作者:
J. M. Lalancette,
J. R. Brindle,
期刊:
Canadian Journal of Chemistry
(NRC Available online 1970)
卷期:
Volume 48,
issue 5
页码: 735-737
ISSN:0008-4042
年代: 1970
DOI:10.1139/v70-121
出版商: NRC Research Press
数据来源: NRC
摘要:
Sulfurated sodium borohydride can reduce oximes to the corresponding amine with yields depending on the steric requirement of the oxime. Intermediate hydroxylamine can be obtained predominantly under appropriate experimental conditions. A reaction mechanism taking into account the availability of only one hydrogen for reduction on the hydride and the production of intermediate hydroxylamine is proposed.
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