Chemorheology of crystalline polymers
作者:
Makoto Yoshinari,
Kenkichi Murakami,
期刊:
Journal of Macromolecular Science, Part B
(Taylor Available online 1982)
卷期:
Volume 21,
issue 1
页码: 85-103
ISSN:0022-2348
年代: 1982
DOI:10.1080/00222348208205087
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Krigbaum's modulus theory and its application to polyethylene which was irradiated with γ-rays are discussed in this article. The results indicate that an amorphous chain in a crystalline polymer varies from an inverse Langevin chain to a Gaussian chain with increasing temperature. Krigbaum's parameter Nn(t), the number of statistical segments present in an amorphous chain when its two ends have just deposited themselves on the surface of a growing crystallite, did not depend on the degree of degradation in a sample. By applying Krigbaum's modulus theory to a degraded sample, it was found that the ratio of the theoretical initial Young's modulus for a degraded sample to that for an undegraded sample, E0(t)/E0(0), increased with the degree of degradation in the sample. It seems to be caused by the greater increase of the degree of crystallinity in a degraded sample with such an increase being expected on the basis of the assumption that, after the amorphous regions in a sample degrade, some of the remaining unsevered amorphous chains can crystallize more readily.
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